Trinkwasser

Safe drinking water access is a human right, but data on safely managed drinking water services (SMDWS) is lacking for more than half of the global population. We estimate SMDWS use in 135 low- and middle-income countries (LMICs) at subnational levels with a geospatial modeling approach, combining existing household survey data with available global geospatial datasets. We estimate that only one in three people used SMDWS in LMICs in 2020 and identified fecal contamination as the primary limiting factor affecting almost half of the population of LMICs. Our results are relevant for raising awareness about the challenges and limitations of current global monitoring approaches and demonstrating how globally available geospatial data can be leveraged to fill data gaps and identify priority areas in LMICs.

Ozonation is used worldwide for drinking water disinfection and increasingly also for micropollutant abatement from wastewater. Identification of transformation products formed during the ozonation of micropollutants is challenging due to several factors including (i) the reactions of both oxidants, ozone and hydroxyl radicals with the micropollutants, as well as with intermediate transformation products, (ii) effects of the water matrix on the ozone and hydroxyl radical chemistry and (iii) the generation of oxidation by-products. In this study, a simple approach to achieve realistic ozonation conditions in the absence of dissolved organic matter has been developed. It is based on composing synthetic water matrices with low-molecular-weight scavenger compounds (phenol, methanol, acetate, and carbonate) that mimic the chemical interactions of ozone and hydroxyl radicals with real water matrices. Synthetic waters composed of only four low-molecular-weight compounds successfully replicated two lake waters and two secondary wastewater effluents, matching instantaneous ozone demand, ozone and hydroxyl radical exposures in the initial phase, as well as the ozone evolution in the second phase of the ozonation process. The synthetic water matrices also reproduced the effects of temperature and pH changes observed in real waters. The abatement of two micropollutants, bezafibrate and atrazine, and the formation of the corresponding transformation products during ozonation were in agreement for synthetic and real waters. Furthermore, the kinetics and extent of bromate formation during ozonation in synthetic water were comparable to real lake water and wastewater. This supports the robustness of the proposed approach because bromate formation is very sensitive to the interplay of ozone and hydroxyl radicals. Furthermore, with the novel reaction system, a significant effect of hydroxyl radicals scavenging by carbonate on bromate formation was demonstrated. Overall, the herein-developed approach based on synthetic water matrices allows to perform realistic ozonation studies including both oxidants, ozone and hydroxyl radicals, without the constraints of using dissolved organic matter.

Cyanobacterial blooms occur at increasing frequency and intensity, notably in freshwater. This leads to the introduction of complex mixtures of their products, i.e., cyano-metabolites, to drinking water treatment plants. To assess the fate of cyano-metabolite mixtures during ozonation, a novel multicompound ozone (O₃) competition kinetics method was developed. Sixteen competitors with known second-order rate constants for their reaction with O₃ ranging between 1 and 10⁸ M^–1 s^–1 were applied to cover a wide range of the O₃ reactivity. The apparent second-order rate constants (k_app,O3) at pH 7 were simultaneously determined for 31 cyano-metabolites. k_app,O3 for olefin- and phenol-containing cyano-metabolites were consistent with their expected reactivity (0.4–1.7 × 10⁶ M^–1 s^–1) while k_app,O3 for tryptophan- and thioether-containing cyano-metabolites were significantly higher than expected (3.4–7.3 × 10⁷ M^–1 s^–1). Cyano-metabolites containing these moieties are predicted to be well abated during ozonation. For cyano-metabolites containing heterocycles, k_app,O3 varied from <10² to 5.0 × 10³ M^–1 s^–1, giving first insights into the O₃ reactivity of this class of compounds. Due to lower O₃ reactivities, heterocycle- and aliphatic amine-containing cyano-metabolites may be only partially degraded by a direct O₃ reaction near circumneutral pH. Hydroxyl radicals, which are formed during ozonation, may be more important for their abatement. This novel multicompound kinetic method allows a high-throughput screening of ozonation kinetics.